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Organic Chemistry 4e Carey | |||||
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| Online Learning Center |
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Self Assessment |
Chapter 4: Alcohols and Alkyl Halides |
Nucleophilic Substitution
Questions
| Qu 1: | (a) Write out the isomers of C4H10O that are alcohols, name them. |
| (b) Identify them as being primary, secondary or tertiary | |
| (c) Arrange them in relative reactivity order towards HBr | |
| Qu 2: | (a) Alcohols react with HBr to give alkyl bromides, whereas there is no reaction with NaBr. Why ? |
| (b) If an alcohol is reacted with NaBr / H2SO4 then the alkyl bromides forms. Why ? | |
| Qu 1: | Calculate the predicted yields for all of the monohalogenated products produced by bromination and chlorination of butane. |
| Qu 2: | On radical chlorination, an isomer of hexane gave a mixture of monochlorides in the ratio 46 : 39 : 15. Identify the isomer. |