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Organic Chemistry 4e Carey | |||||
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Spectroscopy |
Chapter 13: Spectroscopy |
Since spectroscopy is based on the interaction of electromagnetic radiation (EMR) with a molecule, an understanding of electromagnetic radiation is a must.
Spectroscopy monitors the changes in energy states of a molecule, so one must be familiar with the important energy states and concept of quantisation of energy within a molecule.
Electromagnetic Radiation (EMR):The part
of the electromagnetic radiation spectrum that you are most familar with is
"visible light" but this is just a small portion of all the possible types.
Can you think of common applications of other regions
of the electromagnetic spectrum ?
Electromagnetic
radiation has both particle and wave properties. Can you think of an example
of each ?
Wave-like properties:Energy States:
It is important to understand wavelength and frequency and how they relate to one another.Particle-like properties:
A particle of energy is called a photon. Each photon has a discrete amount of energy : a quantum.
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The absorption of
energy causes an atom or molecule to go from an initial energy state (the
ground state) to another higher energy state (an excited state)
The energy changes are frequently described using an energy level diagram.
The energy states
are said to be quantised because there are only certain values that
are possible, there is not a continuous spread of energy levels available.
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