Organic Chemistry 4e Carey
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Chapter 22: Amines
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Project Overview
How to Use This Resource
Nomenclature Quiz
Chapter 1: Chemical Bonding
Chapter 2: Alkanes
Chapter 3: Conformations of Alkanes and Cycloalkanes
Chapter 4: Alcohols and Alkyl Halides
Chapter 5: Structure and Preparation of Alkenes: Elimination Reactions
Chapter 6: Reactions of Alkenes: Addition Reactions
Chapter 7: Stereochemistry
Chapter 8: Nucleophilic Substitution
Chapter 9: Alkynes
Chapter 10: Conjugation in Alkadienes and Allylic Systems
Chapter 11: Arenes and Aromaticity
Chapter 12: Reactions of Arenes. Electrophilic Aromatic Substitution
Chapter 13: Spectroscopy
Chapter 14: Organometallic Compounds
Chapter 15: Alcohols, Diols and Thiols
Chapter 16: Ethers, Epoxides and Sulfides
Chapter 17: Aldehydes and Ketones. Nucleophilic Addition to C=O
Chapter 18: Enols and Enolates
Chapter 19: Carboxylic Acids
Chapter 20: Carboxylic Acid Derivatives. Nucleophilic Acyl Substitution
Chapter 21: Ester Enolates
Chapter 22: Amines
Chapter 23: Aryl Halides
Chapter 24: Phenols
Overview
|
Alkylation of Amines by Alkyl Halides
|
Reaction of Amines with Aldehydes and Ketones
|
Preparation of Amides
|
Hofmann Elimination
|
Electrophilic Aromatic Substitution of Aryl Amines
|
Nitrosation of Amines
|
Preparation of Amides
Chapter 22: Amines
(review of Chapter 20)
Reaction type: Nucleophilic Acyl Substitution
Summary
Primary amines,
R-NH
2
and secondary amines,
R
2
-NH
undergo nucleophilic acyl substitution with carboxylic acid derivatives to give
amides
.
The most common examples are the reactions of acid chlorides and anhydrides, though esters do react with amines.
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