Drawing and Understanding Diagrams
The ability to draw and interpret the different diagrams that are used to represent the different conformations is an important skill to acquire. Maximise your artistic talents ! The only person that will be decieved by your poor diagrams is you ! Your instructor will be able to tell instantly that you are struggling....
These diagrams allow 3D representations of molecules
to be drawn on the 2D world of a piece of paper (or computer screen), in
a similar way to which one can look at the plans for a house.
Usually drawn with two bonds in the plane of the page, one in front, and one behind to give the molecule perspective. When drawing wedge-dash it is a good idea to visualise the tetrahedral arrangement of the groups and try to make the diagram "fit" this. As a suggestion, they seem to be most effective when the "similar" pairs of bonds (2-in-plane, 2-out-of-plane) are next to each other, see below:
Sawhorse diagrams are similar to wedge-dash diagrams, but without trying to use "shading" to denote the perspective. The representation to the right of propane has been drawn so that we are looking at the molecule which is below us and to our left.
These projections are drawn by looking directly along a particular bond in the system (here a C-C bond) and arranging the substituents symmetrically around the atoms at each end of that bond. The protocol requires that the atoms within the central bond are defined as shown below:
In order to draw a Newman projection from a wedge-dash diagram, it is useful to imagine putting your "eye" in line with the central bond in order to look along it.
Let's work through an example, consider drawing a Newman projection by looking at the following wedge-dash diagram of propane from the left hand side.
Drawing cyclohexane so that it looks like a chair can be the key to appreciating the axial and equatorial positions. If you are unable to draw good looking structures that clearly show axial and equatorial positions, then your instructor is probably going to assume that you don't know.
By not mastering the trick of drawing cyclohexanes the only person that really suffers is you the student. You deprive yourself of the knowledge and the chance to appreciate it and what it means. Believe me, it will be needed later.
The first step is drawing the chair itself. Although the chair "looks better" when slightly angled, it maybe easier to "learn" to draw it with the middle portion horizontal.