The discharge tube is filled with hydrogen gas. When a high voltage electrical discharge energizes the gaseous atoms, light is emitted only at specific wavelengths. The emission spectra obtained are called line spectra, due to the appearance of bright lines.
In the hydrogen emission spectrum there are 4 lines in the visible region. A purple line at a wavelength of 411 nanometers, a dark blue line at a wavelength of 434 nanometers, a green line at a wavelength of 486 nanometers, and an orange-red line at a wavelength of 656 nanometers. Let's look at the electronic transitions responsible for the observed line spectra.
When an electron drops from a higher energy orbit to a lower energy orbit, a quantum of energy, a photon, is given off in the form of light. During the electronic transitions shown, light is emitted in the visible region of the electromagnetic spectrum. You may click on the buttons to review each of the individually.